Administrative Rules for
PART 201 ENVIRONMENTAL REMEDIATION
of the Natural Resources and Environmental Protection Act 1994 PA 451, as
amended
Rule 724.
(1) Indoor inhalation of hazardous substance
vapors volatilizing to indoor air from soil shall be considered a reasonable
and relevant exposure pathway only for hazardous substances that have a Henry's
law constant greater than or equal to 0.00001 atm-m3/mole.
(2) Except as provided in subrule (1) of this rule, if any of the following
conditions exist, the generic criteria developed pursuant to this rule shall
not apply and a site-specific evaluation of indoor inhalation risks shall be
conducted:
(a) There is a structure present or planned to be
constructed at the facility which does not have a concrete block or poured
concrete floor and walls.
(b) There is a sump present that is not
completely isolated from the surrounding soil by its materials of construction.
(3) Soil cleanup criteria based on indoor
inhalation of volatile emissions from hazardous substances in soil shall be
called soil volatilization indoor air inhalation criteria ("SVIIC"). The SVIIC is determined by the following
series of calculations, except as provided in R 299.5734(3):
equation
for Carcinogenic effects:
where,
|
SVIIC |
(Soil
volatilization indoor air inhalation criterion) |
= chemical-specific, ug/kg |
|
TR |
(Target
risk level) |
= 10-5 |
|
AT |
(Averaging
time) |
= 25,550 days (70 x 365) |
|
AIR |
(Adjusted
inhalation rate) |
= 1 (residential) = 2 (commercial/industrial) |
|
IURF |
(Inhalation
unit risk factor) |
= chemical-specific, (ug/m3)-1 |
|
EF |
(Exposure
frequency) |
= 350 days/year (residential) = 245 days/year (commercial/industrial) |
|
ED |
(Exposure
duration) |
= 30 years (residential) = 21 years (commercial/industrial) |
|
CRbuilding |
(Ratio
of indoor air concentration to soil concentration) |
= chemical-specific, (ug/m3)/(ug/kg) |
Equation
for Noncarcinogenic effects:
![]()
where,
|
SVIIC |
(Soil
volatilization indoor air inhalation criterion) |
= chemical-specific, ug/kg |
|
THQ |
(Target
hazard quotient) |
= 1 |
|
AT |
(Averaging
time) |
= 10,950 days (residential) = 7,665 days (commercial/ industrial) |
|
EF |
(Exposure
frequency) |
= 350 days/year (residential) = 245 days/year (commercial/industrial) |
|
ED |
(Exposure
duration) |
= 30 years (residential) = 21 years (commercial/ industrial) |
|
ITSL |
(Initial
threshold screening level) |
= chemical-specific, ug/m3 |
|
CRbuilding |
(Ratio
of indoor air concentration to soil concentration) |
= chemical-specific, (ug/m3)/(ug/kg) |
The
contaminant vapor concentration in the building indoor air is written as:
where,
|
CRbuilding |
(Ratio
of indoor air concentration to soil concentration) |
= chemical-specific, (ug/m3)/(ug/kg) |
|
a |
(Attenuation
coefficient) |
= chemical-specific, unitless |
|
|
(Ratio
of soil vapor concentration to soil/source concentration) |
= chemical-specific, (ug/m3)/(ug/kg) |
The
vapor-phase contaminant concentration at the source for soil is written as:
where,
|
|
(Ratio
of soil vapor concentration to soil/source concentration) |
= chemical-specific, (ug/m3)/(ug/kg) |
|
H' |
(Dimensionless
Henry's law constant, where H' = HLC x 41) |
= chemical-specific, unitless |
|
HLC |
(Henry's
law constant at 25 degrees Celsius) |
= chemical-specific, (atm-m3/mol) |
|
TAF |
(Temperature
adjustment factor) |
= 0.5, unitless |
|
|
(Uniform
concentration in soil) |
= 1 ug/kg |
|
|
(Dry
soil bulk density) |
= 1.5 g/cm3 |
|
|
(Soil
water-filled porosity) |
= 0.3 cm3/cm3 |
|
|
(Soil-water
partition coefficient) |
= chemical-specific, cm3/g (equivalent to L/kg) |
|
|
For organic compounds |
= Koc (cm3/g) x foc (g/g) |
|
|
For inorganic compounds |
= chemical-specific, cm3/g |
|
|
(Soil
organic carbon partition coefficient) |
= chemical-specific, cm3/g |
|
|
(Fraction
of organic carbon content of soil) |
= 0.002 g/g (0.2%) |
|
|
(Soil
air-filled porosity) |
= 0.13 cm3/cm3 |
The
intrusion rate of hazardous substance vapors into buildings is predicted using
an analytical solution which couples both diffusive and convective transport of
vapors emanating from subsurface soil into enclosed spaces. An attenuation coefficient (a) is
calculated that is expressed as the ratio of building indoor air concentration
to the vapor-phase concentration at the source.
Values of a are calculated assuming
infinite source conditions. For infinite
source conditions a is written as follows:

where,
|
a |
(Attenuation
coefficient) |
= unitless |
|
|
(Effective
diffusion coefficient through vadose zone) |
=
chemical-specific, cm2/s |
|
Dcrack |
(Effective
diffusion coefficient through crack) |
= cm2/s,
(Dcrack =
equation for |
|
Ab |
(Area
of enclosed space below grade) |
= 1.96E+6
cm2 (residential) = 3.83E+6
cm2 (commercial/
industrial) |
|
Qbuilding |
(Building
ventilation rate) |
= 1.51E+5
cm3/s (residential) = 5.04E+5
cm3/s (commercial/ industrial) |
|
Lcrack |
(Building
foundation thickness) |
= 15 cm |
|
LT |
(Source-building
separation distance) |
= 15 cm (All land use categories) |
|
Qsoil |
(Volumetric
flow rate of soil vapor into the building) |
= 0.81 cm3/s (residential) = 2.10 cm3/s (commercial/ industrial) |
|
Acrack |
(Total
area of cracks below grade) |
= 196 cm2 (residential) = 383 cm2 (commercial/ industrial) |
|
exp(p) |
(The
base of the natural logarithm raised to power p) |
= ep |
The
effective diffusion coefficient calculation for the vadose zone (
) is written as:
![]()
where,
|
|
(Effective
diffusion coefficient through vadose zone) |
= chemical-specific, cm2/s |
|
Da |
(Diffusivity
in air) |
= chemical-specific, cm2/s |
|
qa |
(Soil
air-filled porosity) |
= 0.13 cm3/cm3 |
|
n |
(Total
soil porosity) |
= 0.43 cm3/cm3 |
|
Dw |
(Diffusivity
in water) |
= chemical-specific, cm2/s |
|
H' |
(Dimensionless
Henry's law constant, where H' = HLC x 41) |
= chemical-specific, unitless |
|
HLC |
(Henry's
law constant |
= chemical-specific, (atm-m3/mol) |
|
qw |
(Soil
water-filled porosity) |
= 0.3 cm3/cm3 |
(4) Facility-specific measurements of the
following parameters may be substituted individually for the generic assumptions
and still allow the facility to satisfy the categorical criteria in section
20120a(1)(a) to (e) of the act:
(a) Dry soil bulk density.
(b) Fraction of organic carbon in soil.
(c) Soil vapor permeability.
(d) Temperature adjustment factor for Henry's law
constant.
Facility-specific measurements shall be based on representative
characterization. documentation of all
facility specific values shall be provided in the remedial action plan.
(5)
The department may approve of methods to demonstrate compliance with
criteria for this exposure pathway if those methods are more representative of
in-situ conditions at the facility.
Methods acceptable to the department may include, but are not limited
to, evaluation of representative soil gas concentrations.
(6) A
site-specific SVIIC may be developed for remedial action plans prepared
pursuant to section 20120a(2) of the act
that is based on demonstration of compliance with 1974 PA 154, MCL 408.1001 et
seq. and the rules promulgated pursuant to that act. This subrule shall apply only when all of the
following conditions are satisfied:
(a) The risk being evaluated results from
inhalation by workers of hazardous substances in indoor air within an active
workplace that is regulated by 1974 PA 154, MCL 408.1001 et seq. and the rules
promulgated pursuant to that act.
(b) The exposure to hazardous substances from
environmental contamination is a portion of the exposure to which workers are
otherwise subject from process-related sources of the same hazardous substance.
(c) The risk to the non-worker population, if
any, from inhalation of indoor air at the property has been evaluated using
generic residential GVIIC or a site-specific evaluation has been conducted for
the non-worker population according to methods acceptable to the department,
and the risk is not unacceptable on the basis of the risk management objectives
set forth in section 20120a of the act.
These administrative rules are provided as a free
service of the State Bar of Michigan Environmental Law Section. The administrative rules, which were
re-formatted for consistency, are not intended to replace official versions and
are subject to revision and/or repeal. The Environmental Law Section presents this information, without
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